That would be pretty interesting actually. Sir Roger Moore's build could be all about using smarm, persuasion and smutty seduction to get through missions. He'd probably be up for voicing some of it, too, he loves a bit of publicity.
I would love to see something like Alpha Protocol attempted with the 007 license. It'd be perfect in setting up this concept of playing like any of the 007's, and kinda fitting in a Daniel Craig skill set build, or a Sean Connery skill set build, or Pierce Brosnan, etc.