Invective is a decent shotgun for MP, but there are better exotics shotguns (and also better legendary shotguns). Juju is pretty useless in PVP (as are pulse rifles in general). If you're strictly looking for a PVP weapon, Thorn is the best of those bounties.
Honestly, depends on your playstyle and weapon preferences. I use a pre-expansion Vanquisher AR (New Monarchy vendor; the expansion Vanquisher has worse perks but it's still probably the best high impact, low ROF vendor AR), a Hide and Seek shotgun with some decent perks (though mostly any shotgun will do, really; shotgun play is more about just being a better player than the other person), and a Truth as my exotic. The only thing I could universally recommend would be Truth, but, unfortunately for you, Xur was just selling it last weekend, so odds are you won't see it for sale for another long while, but maybe you'll get lucky and he will or you'll get it from a Nightfall. Before I got the Truth, I was using a random drop Swarm (high impact, low ROF LMG) that had increased accuracy while crouching and fast reload after a kill, and that did really well for me, but Truth is just too hilariously broken to not use.
As for stuff I don't use, a lot of people use Plan C or Pocket Infinity (or now Murmur, from TDB quest storyline) if you're into fusion rifles. Suros Regime is still pretty popular, as are Thorn, Hawkmoon (if you're on Sony), Vex Mythoclast, Praedyth's Revenge, and Found Verdict, but this has basically just turned into 'me listing out most of the good weapons in the game.'
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