1. Don't be greedy. You are more useful alive than dead, even with +1 kill. Especially in later parts of the game.
2. Try to pay attention to your minimap. Try to see what your team is doing and work with them. The most coordinated team wins. Also pay attention to how many enemies are visible. If one or more are missing, be prepared for a gank attempt and don't push out far without at least as many teammates.
3. Play matchmaking after you understand the absolute basics. I think you will have more fun/learn more than playing practice games.
4. Health always wins early game. Get a health item or at least a couple health pots. Try to figure out if their team is unbalanced towards magic or physical damage and compensate by buying a countering resist item. Remember, though, that resist items are much less valuable if you have a small health pool. Get Mercury's Treads if they have a lot of stuns. A big mistake I see new players making is never buying any defensive items. Don't go overboard, but a good balance makes a huge difference.
5. Don't worry about learning the specifics of every champion or about playing every one. Find one you enjoy and then try to get good with it. All you need to learn about other champions is, “what can this champion do to me in x situation?” Just pay attention to what your enemies are doing as you're playing and you'll learn what you need to know about all the champions eventually (be grateful, there are about three times as many heroes in DotA).
I think that casters might be more difficult to play for newer players, so look at tanks and physical damage champions.
There are a bunch of these threads on the LoL forums if you look or search in the Guides/Strategy section, as well.
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