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The Chameleon is actually one of Spider-man's earliest super-villains. A master impersonator, he uses his costumes for villainy and fun.
Doctor Otto Octavius was a scientist who turned to a life of crime, using a set of four flexible mechanical arms originally designed to assist in scientific research and labwork to give himself a major advantage over the police.
The Green Goblin is Norman Osborn, a businessman and scientist who injected himself with an experimental serum to test it. The serum granted him immense strength, but also drove him insane. He is considered the arch nemesis of Spiderman. He is known for using his glider and pumpkin bombs.
The Hobgoblin is a Spider-Man villain. Roderick Kingsley, a fashion designer with connections to the criminal underworld, became the Hobgoblin when he discovered a cache of weapons and a glider left by the Green Goblin.
The Kingpin, aka Wilson Fisk, is the biggest crime lord in New York City, and possibly the world. He operates under the guise of a legitimate businessman and philanthropist, much to the chagrin of Spider-Man, Daredevil, and the Punisher.
Mysterio is a villain from Marvel Comics. He is specifically Spider-Man's enemy. He is recognized by his large fishbowl helmet and his use of illusion. He was portrayed by Jake Gyllenhaal in Spider-Man: Far From Home (2019).
Rhino is a nemesis of Spider-Man. His costume gives him superhuman durability and strength.
Scorpion is a nemesis of Spider-Man. He was once private investigator Mac Gargan, until J. Jonah Jameson hired him to be the subject of an experiment that gave him immense strength, a costume with a tail that fires lasers, and the deep-down crazies. He was the third Venom.
With a terrible track record, a costume resembling a soiled mattress, and a name that inspires fear for all the wrong reasons, the Shocker is primarily a laughingstock. This Spider-Man villain has gauntlets that allow him to generate powerful shockwaves.
Mob boss and enemy of Spider-Man.
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