@rempresent: As I understand it, Valve will be implementing a mentoring system after launch of the game proper. They have about 15 heroes to add, and then balance changes after that, so it could be some time yet. I heard a rumour that they're aiming to launch this year though.
In the meantime, YouTube is a great resource, there are playlists that cover the whole gamut from roles to laning to item builds etc. I have found Purge's videos to be helpful and less patronising than many others, so I'd recommend you take a look there. Additionally, here is a beginner's playlist - I have watched only a few of the videos listed, but it should be helpful.
I'd recommend you learn what distinguishes the various roles such as carry, support, pusher etc. as it will help you to understand what players are trying to do and when, when you're watching a game/video. I can go into a bit more detail about these if you want, but a) I'm far from great at the game myself and b) I don't know what you already know about the game. (Just @ me if you want a reply, as I don't usually monitor the forums)
One thing to be aware of is that Valve's role categories (eg. carry, disabler etc.) are not perfect. For instance Anti-Mage, Faceless Void and Morphling are "hard carries", and come into their own very late in the game, yet no distinction is made in-game about them; you just have to discover it for yourself.
Hope some of that helps!
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