It's got to be Season 2's finale. You got Jeffster performing Mr. Roboto to an awesome wedding shootout, leading to one of the greatest lines ever: "Why are you letting Sam Kinison and an indian lesbian ruin your wedding?" Then Chuck finally embracing the idea of being the intersect and choosing to become the Intersect 2.0. All leading up to him kicking ass to John's dumbfounded "Chuck me!", and ending with a great Matrix homage, "Guys, I know Kung Fu."
I only clicked on this post because of how much I hate the phrase "I could care less." I was pleasantly surprised with what I found. The correct form is indeed "I couldn't care less."
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