King is pretty easy to pick up and play, with his lengthy standard punch combo, powerful grapples, and some nice surprise moves. So is Bryan, since he has a great defense and plenty of powerful combos and techniques. Jin and Kazuya are probably the most balanced, with some spammable kick combos, decent health and power.
Kuma's probably the easiest "power" type character to pick up and play since his three-punch combo is rather devastating. Steve Fox is insanely quick if you know how to use his dodge system, and you could probably take out the final boss with him easily if you can dodge right...
I don't really know. Tekken is a very mash-friendly series, but has a lot of technical stuff under the surface. I say go with Siris, and just play as anyone you can until you find someone you're really good with.
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