If you want something for a show you should probably start with some of the impressive graphics, you've already shown Defender of the Crown (You should probably mention the correct year for that game) but there are other Cinemaware games. Some flight simulator would probably be a good idea F/A-18 Infiltrator is kind of easy to run and you can enjoy the spectacular view of your local area. Pretty much anything from Psygnosis should also work and for something more obscure The Guild of Thieves.
Other games of interest:
Dungeon Master (I think this has been shown already also)
Wings!
Populous, or perhaps Populous II will look better and be a bit more intuitive.
One of the Pinball games.
Some shoot-em up, I like the Xenon II music but there are lot of alternatives like Battle Squadron, Katakis or R-Type.
@sinusoidal: If you actually survive 10 minutes you might have a drinking problem... I think I counted 30 swears during the first minute of that video and noone even says anything for the first 12 seconds of it.
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