I don't believe they add them to the system. Sony's trophy system has been messed up in that way for a long time. It takes trophies from new games forever to show up on their website as well. Giant Bomb only pulls the data from Sony. This was an issue when they first started implementing the trophy system as well. The U.S. website didn't have a ton of trophies that the EU site did, so they started to pull data from there as well.
When searching your PSN ID on Sony's US site XCOM does not show up.
Edit: Neither does RE6
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